Toxics Use Reduction Institute
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 October 12, 2016 
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 This is the bi-weekly bulletin of the TURI Library at the University of Massachusetts Lowell. Greenlist Bulletin provides previews of recent publications and websites relevant to reducing the use of toxic chemicals by industries, businesses, communities, individuals and government. You are welcome to send a message to mary@turi.org if you would like more information on any of the articles listed here, or if this email is not displaying properly. 
  
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 Plastic substitutes and other breakthroughs from 25 years of green chemistry      
Source: The Guardian, October 6, 2016 Author: Bruce Watson
 
 This year, green chemistry celebrates its 25th birthday. The science of finding more sustainable and less toxic chemicals was once a revolutionary idea, but has since become a part of the consumer product landscape. From removing carcinogens from furniture to banning ineffective antibacterial chemicals, the struggle to create a healthier and more sustainable chemical landscape continues to attract widespread attention.
 
  Customers -- and companies -- are taking note. A recent survey estimates that the global market for green chemicals is on track to grow from $11bn in 2015 to $100bn in 2020. In North America, the numbers are expected to go from $3bn to $20bn in the same period.
 
  As green chemistry prepares to enter its next quarter century, we asked some pioneers in the field to tell us about some of its most important advancements. 
 
  Read more...
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 EPA Acts on New Chemical Law to Fast-Track Five Chemicals     
Source: U.S. Environmental Protection Agency, October 11, 2016
 
 WASHINGTON -- EPA is taking swift steps to carry out  requirements in the Frank R. Lautenberg Chemical Safety for the 21st  Century Act to reform the Toxic Substances Control Act and to reduce  exposure to certain persistent, bioaccumulative, and toxic (PBT)  chemicals.
 
  "The threats from persistent, bioaccumulative and toxic chemicals are  well-documented," said Jim Jones, assistant administrator in EPA's  office of chemical safety and pollution prevention. "The new law directs  us to expedite action to reduce risks for these chemicals, rather than  spending more time evaluating them. We are working to ensure the Frank  R. Lautenberg Chemical Safety Act signed in June of this year delivers  on the promise of better protecting the environment and public health as  quickly as possible."
 
  The five chemicals to receive expedited action are: - Decabromodiphenyl ethers (DecaBDE), used as a flame retardant in textiles, plastics and polyurethane foam;
 - Hexachlorobutadiene (HCBD), used in the manufacture of rubber compounds and lubricants and as a solvent;
 - Pentachlorothio-phenol (PCTP), used as an agent to make rubber more pliable in industrial uses;
 - Tris (4-isopropylphenyl) phosphate, used as a flame retardant in consumer products and other industrial uses; and
 - 2,4,6-Tris(tert-butyl)phenol, used as a fuel, oil, gasoline or lubricant additive.
  Read more...
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 CMR substances not automatically banned in cosmetics    
Source: Chemical Watch, October 6, 2016 Author: Vanessa Zainzinger
 
 Carcinogenic, mutagenic or reprotoxic (CMR) substances are not automatically banned for their use in cosmetic products, if they have a mandatory classification as such under the CLP (Classification, Labeling and Packaging) Regulation.
 
  The European Commission confirmed this at September's meeting of its cosmetics working group. ...
  This says in general, category 1 and 2 CMR substances are prohibited for  use in cosmetics. However, there are exemptions. Category 2 CMRs can be  used if deemed safe by the European Commission's Scientific Committee  for Consumer Safety (SCCS). Category 1 CMRs can be used if the SCCS  decides it would be safe, and if three other criteria set out in the  Article are also met.
 
  Read more...
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 New Report from Senator Markey Details Widespread Presence of Toxic Chemicals in Nation's Schools   
Source: U.S. Senator Ed Markey's Office, October 5, 2016
 
 Washington (October 5, 2016) -- Up to 14 million students nationwide, representing nearly 30 percent of America's school-aged population may be exposed to toxic chemicals called PCBs in their schools. That's just one finding from Senator Edward J. Markey's (D-Mass.) new report, "The ABC's of PCBs: A Toxic Threat to America's Schools", which details the presence of polychlorinated biphenyls (PCBs), a class of man-made chemicals linked to cancer and other health problems, that are found in school building materials and equipment across the country. The report details how children in schools across the country may be unknowingly exposed to PCBs, that there are generally no requirements for schools to do testing or inspections to ensure PCB exposures aren't happening, and that even when exposure is identified, reporting and remediation of PCB hazards are inconsistent and often ineffective. The report includes case studies from California, Massachusetts and New York on school districts that have identified PCB hazards in local schools.
 
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 Duty to prevent childhood exposure
  
Source: UN Special Rapporteur On Human Rights & Toxics, September 15, 2016 Author: Baskut Tuncak
 
 The best interests of the child should  be at the heart of decision making when it comes to protecting  children's rights to life, survival and development, health, freedom  from the worst forms of child labour, and also to safe food, water and  housing. The UN Convention on the Rights of the Child explicitly links  children's right to health with pollution and contamination, but there  are still systemic failures to realizing children's rights in the  context of toxic chemicals.
 
  Childhood exposure to toxic substances  in every part of the world has created a "silent pandemic" of disease  and disability affecting millions of children and adults. Rates of  disease and disability linked to childhood exposure to toxic chemicals  have increased around the world at rates that can not be explained by  genetics or lifestyle choices, leaving toxic chemicals and pollution as a  major contributing factor. Recent cases have called into question how  effectively States are protecting human rights when it comes to toxics,  and children's rights are arguably the most at risk. The World Health  Organisation estimates that more than 1,700,000 children under the age  of five died prematurely from modifiable environmental factors; but  these figures are only the tip of the iceberg when it comes to death,  disease and disability linked to toxics and pollution.   Read more...
  See the "Report of the Special Rapporteur on the implications for human rights of the environmentally sound management and disposal of hazardous substances and wastes".
  Also see, "Former Samsung worker's death from cancer at 22 kicked off campaign".  
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 Development of a Waterborne, Zero-VOC DTM (direct-to-metal) with Excellent Corrosion Resistance  
Source: Paint & Coatings Industry, October 1, 2016 Authors: Richard Flecksteiner, Terri John, and Cassandra Giorgio
 
 A well-formed hydrophobic film that is impervious to water and salts  is required to prevent corrosion of painted metal surfaces. One of the  most effective ways to ensure that the film is well formed is through  the use of coalescing solvents. The ability of a coating to form a  protective film becomes more difficult as the amount of coalescent in  the coating formulation decreases. At the same time, coatings  manufacturers are interested in reducing the amount of volatile organic  compounds (VOCs) in their coatings. This trend is driven both by  regulation as well as consumer preference.
 
  
One way to reduce the amount of coalescent in the coatings is to  reduce the minimum film formation temperature (MFFT) of the polymer. The  most obvious way to accomplish this is to reduce the glass transition  temperature (Tg) of the polymer. Unfortunately, this will also reduce  the hardness and dirt pickup resistance of the coatings. Through the use  of designed particle morphology and process conditions we have  developed a latex that can be formulated into a coating without the use  of coalescing solvents that gives excellent corrosion resistance,  adhesion to steel, and still is hard enough to give good block  resistance and dirt pickup resistance.
 
  
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 Want sharper workers? Try a green-certified office  
Source: GreenBiz.com, October 7, 2016 Author: Elsa Wenzel
 
 LOS ANGELES -- Can a green building make your company smarter? That's what new research suggests, underscoring the ROI for green certifications -- not just for optimizing the usual factors like energy and water use, but for elevating workforce productivity.
 
  It's  clear at Greenbuild 2016 this week that the health and wellness of  workers indoors is becoming a high-level concern. No longer is human  comfort something a corporation might consider from the kindness of its  profit-seeking heart. Instead, evidence of a competitive advantage for  fostering well-being speaks the language of the C-suite.
 
  The early results of a new study dubbed COGFX are being buzzed about for finding 26-percent higher scores on cognitive tests for workers in LEED-certified buildings.    Read more...
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 Phthalates in Fast Food: A Potential Dietary Source of Exposure  Source: Environmental Health Perspectives, October 2016 Author: Wendee Nicole
 
 Many research studies have surveyed nutritional habits, but fewer have studied how food processing and packaging might introduce unwanted chemicals into foods. In this issue of EHP, researchers report that fast food consumption appears to be one source of exposure to the chemicals di(2-ethylhexyl) phthalate (DEHP) and diisononyl phthalate (DiNP).
 
  The authors used data from the National Health and Nutrition Examination Survey (NHANES) to estimate the percentage of individuals' calories that came from fast food, fat intake attributable to fast food consumption, and fast food intake by food group. During NHANES interviews, respondents had reported their diet from the preceding 24 hours. Fast food was defined as food obtained from restaurants without waiter service and from pizza restaurants, as well as all carryout and delivery food. Regression analyses were used to determine associations between fast food consumption and urinary concentrations of DEHP metabolites, DiNP metabolites, and bisphenol A (BPA).
 
  Read more...
  Also see from EHP, "Recent Fast Food Consumption and Bisphenol A and Phthalates Exposures among the U.S. Population in NHANES, 2003-2010", and "Toward a Better Beauty Regimen: Reducing Potential EDC Exposures from Personal Care Products".
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 Surface degradation and nanoparticle release of a commercial nanosilica/polyurethane coating under UV exposure  Source: Journal of Coatings and Technology Research, September 2016 Authors: Deborah S. Jacobs, Sin-Ru Huang, Yu-Lun Cheng, Savelas A. Rabb, Justin M. Gorham, Peter J. Krommenhoek, Lee L. Yu, Tinh Nguyen, Lipiin Sung
 
 Many coating properties such as mechanical, electrical, and ultraviolet (UV) resistance are greatly enhanced by the addition of nanoparticles, which can potentially increase the use of nanocoatings for many outdoor applications. However, because polymers used in all coatings are susceptible to degradation by weathering, nanoparticles in a coating may be brought to the surface and released into the environment during the life cycle of a nanocoating. Therefore, the goal of this study is to investigate the process and mechanism of surface degradation and potential particle release from a commercial nanosilica/polyurethane coating under accelerated UV exposure. Recent research at the National Institute of Standards and Technology (NIST) has shown that the matrix in an epoxy nanocomposite undergoes photodegradation during exposure to UV radiation, resulting in surface accumulation of nanoparticles and subsequent release from the composite. ...
  The results demonstrated that the added silica nanoparticle solution decreased the photodegradation rate (i.e., stabilization) of the commercial PU nanocoating. Although the degradation was slower than the previous nanosilica epoxy model system, the degradation of the PU matrix resulted in accumulation of silica nanoparticles on the nanocoating surface and release to the environment by simulated rain. These experimental data are valuable for developing models to predict the long-term release of nanosilica from commercial PU nanocoatings used outdoors and, therefore, are essential for assessing the health and environmental risks during the service life of exterior PU nanocoatings.
  
 
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 Greenlist Bulletin is compiled by:
  
Mary Butow
  
Research and Reference Specialist
  
Toxics Use Reduction Institute
  
University of Massachusetts Lowell
  
600 Suffolk Street, Wannalancit Mills Suite 501
  
Lowell, MA 01854-2866
  
978-934-4365
  
978-934-3050 (fax)
  
mary@turi.org
  
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