You Have the Right to Know, Part 3
Upon Further Review.... In our continuing series on the MSDS we will discuss sections 5 through 8. In the last issue of our Training Newsletter we discussed sections 1 through 4. Below is a listing of all sections of an MSDS; we are using the 16 section MSDS ASNI version which will be the industry standard in June 2015. The MSDS we are using is for starting fluid for a skiff. The name of the product is Jump Start Starting Fluid with Lubricity. There will be a short quiz at the end of this article The 16 Sections are: - Identification of the product
- Hazard(s) identification
- Composition/information on Ingredients
- First Aid measures
- Firefighting measures
- Accidental Release measures
- Handling and storage
- Exposure control/personal protection
- Physical and chemical properties
- Stability and reactivity
- Toxicological information
- Ecological information
- Disposal considerations
- Transport information
- Regulatory information
- Other information
Section 5: FIRE FIGHTING MEASURES This section will discuss the flammability, extinguishing method, and explosion hazards of the product. Flammable Properties: This product is extremely flammable is accordance with aerosol flammability definitions. This section will list the flashpoint, auto ignition temperature, upper explosive limit and lower explosion limit. Fire and Explosion Data: SUITABLE EXTINGUISHING Method: Carbon dioxide foam, dry chemical, Class B extinguishers. PRODUCTS OF COMBUSTION: Oxides of carbon EXPLOSION HAZARDS: Aerosol containers when exposed to heat from fire, may build pressure and explode. Vapors may accumulate in a confined space and create a flammable atmosphere. PROTECTION OF FIRE FIGHTERS: Firefighters should wear self-contained breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire exposed containers cool and knock down vapors. Section 6: ACCIDENTAL RELEASE MEASURES This section will discuss what procedures and precautions to be used in the event of area lease of the product such as a spill. PERSONAL PRECAUTIONS: What PPE to use. Listed in Section 8 ENVIRONMENTAL PRECAUTIONS: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or drains. METHODS FOR CONTAINMENT AND CLEAN UP: Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, cleanup workers should wear appropriate respiratory protection listed in section 8. Recovered or absorb spill material using an absorbent designed for chemical spills. Place used absorbent materials into proper waste containers. Section 7: HANDLING AND STORAGE This section will discuss the proper handling and storage procedures for the product. HANDLING PROCEDURES: Do not use near open flames, heat, or any sources of ignition. Vapors are heavier than air and will collect in low areas. Use proper ventilation that will remove vapors from low areas. Avoid prolonged or repeated contact with the skin. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. STORAGE PROCEDURES: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120 F to prevent cans from rupturing. Do not store near sources of ignition. Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION This section will discuss exposure guidelines, controls, and PPE for the product. Exposure Guideline: This part will cover the components that make up the product which includes: Diethyl Ether, Heptane, Carbon Dioxide, and an upper cylinder lubricant. This part will also list the established OSHA levels for exposure in TWA (time weighted average in an 8 hour period for PEL (personal exposure limit) and STEL (short term exposure limit) in regards to the product. Controls and Protection: ENGINEERING CONTROLS: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the containment at the source. RESPIRATORY PROTECTION: None is required for normal work where adequate ventilation is provided. Use a self-contained breathing apparatus in confined spaces and emergencies. EYE/FACE PROTECTION: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. SKIN PROTECTION: Use protective gloves such as Nitrile or neoprene. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. QUIZ (From TNL Issue 8 April 16, 2014) 1. Presently there are to 2 optional MSDS'S in use. The 8 section OSHA MSDS and THE 16 section ASNI version. True ____ False ____ 2. In section 1 of the MSDS - Identification, there will not only be the manufacturer's phone number but also a 24 hour emergency contact number. True____ False____ 3. Section 2 of the MSDS is: 1. Composition/Information on ingredients_____ 2. First Aid Measures_____ 3. Hazards Identification______ 4. Handling and Storage______ 4. In Section 4 of the MSDS - First Aid Measures, is where you will find the "Note to Physician" which gives specific care instructions for a physician and any treatment that might be listed should not be done by a non-medical person. True ____ False____ |